Also when you get a small table giving a specific compounding on it asks when does each undergo "hydrogen bonding when in aqueous solution", how do you know the answer is yes or no?
does the hydrogen bonding only take place when H bonds with a certain element?
This question is primarily asking if you can identify molecules with a permanent dipole, as that's necessary for hydrogen bonding to occur. So yes, you're only going to see this when hydrogen is bonded to a highly elecronegative element in a configuration that results in a net dipole.
As for naming, just review the IUPAC rules. They pretty clearly spell out what comes before what. That's just a simple memorization task.
For stereochemistry, you need two things:
1) Be able to orient molecules in space to place the hydrogen (or lowest ranking element/group) extending back into the page
2) Remember which elements take precedence over which so you know which way to count. The general rule is the higher the atomic number, the higher the precedence.