I get what you're saying
In round one you have a 33% chance of picking the right door and a 66% chance of picking the wrong door. If you switch doors in round two, you've essentially taken those 66% odds.
I not sure I buy it as anything more than a probability anomaly, but I do understand what you're saying.
Just to elaborate a little, choosing to switch in round 2 is either a guaranteed W or a guaranteed L, you just don't know which of those it is since the doors are hiding that information. Some all-seeing observer who knows what's behind each door will already be able to tell you whether switching is a guaranteed W or L as soon as you make your initial choice. Whether switching is a guaranteed L or a guaranteed W depends on your initial choice. If you chose the car initially (1/3 chance), switching is a guaranteed L. If you chose a goat initially (2/3 chance), switching is a guaranteed W.